First ZnGa2O4 transparent ceramics

نویسندگان

چکیده

Transparent polycrystalline ZnGa 2 O 4 ceramics are synthesized, for the first time, by combining high-energy ball milling, solid-state reaction and spark plasma sintering. They appear transparent in both visible near infrared (up to 9 μm) ranges after a post-SPS annealing air converting raw semiconductor into an electrical insulator. The maximum of transmittance is reached region, at around 2.5 μm, with value 78 % (1 mm thick sample) close previously measured single crystals. These present classic cubic spinel structure dense microstructure (> 99 %) attained without sintering aids, average grain size 600 nm random orientation crystallites. TEM observations performed on thin foils have revealed limited nanometer scale intergranular porosity which does not affect much transparency. As proof interest, red long-lasting luminescence arising from entire sample volume observed these Cr 3+ doped ceramics. This innovative work anticipated further drive development towards wider range performing optical applications such as laser emission.

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ژورنال

عنوان ژورنال: Journal of The European Ceramic Society

سال: 2021

ISSN: ['0955-2219', '1873-619X']

DOI: https://doi.org/10.1016/j.jeurceramsoc.2021.03.038